Stanley Tucci and wife Felicity Blunt hit it off right away when they first met - despite having a 21-year age gap. "I wasn't sure that I would ever remarry," Tucci, 65, said in an October 2024 conversation with Jenna Bush Hager, which aired during the Thursday, May 7, episode of her "Open Book With Jenna" podcast. The Devil Wears Prada star was married to first wife Kate Tucci from 1995 until her death at age 47 following a breast cancer battle in 2009. Before she died, the couple welcomed twins Isabel and Nicolo, 26, and daughter Camilla, 24.