The early aughts were full of great celebrity couples - Brad and Jen, Britney and Justin, Ben and Jen (Part 1) - but sometimes we're just as fascinated by those who flew a little more under the radar. Years before she married Justin Timberlake, Jessica Biel was in a serious, long-term relationship with another famous heartthrob: Chris Evans. Let's look back at their relationship and figure out if she loved him even more than she loved wearing jeans and a nice top to red carpet events.